Electrochemical Dechlorination of 4-Chlorophenol to Phenol
نویسندگان
چکیده
منابع مشابه
Regiospecificity of chlorophenol reductive dechlorination by vitamin b(12s).
Vitamin B(12), reduced by titanium (III) citrate to vitamin B(12s), catalyzes the reductive dechlorination of chlorophenols. Reductive dechlorination of pentachlorophenol and of all tetrachlorophenol and trichlorophenol isomers was observed. Reaction of various chlorophenols with vitamin B(12) favored reductive dechlorination at positions adjacent to another chlorinated carbon, but chlorines or...
متن کاملReductive dechlorination of p-chlorophenol by nanoscale iron.
OBJECTIVE To investigate reductive dechlorination of 4-chlorophenol (4-CP) by nanoscale Fe0 under different conditions. METHODS Nanoscale Fe0 was synthesized by using reductive method. 4-CP and its intermediate products were analyzed by HPLC. Chlorine ion was quantified with DX-100 ion chromatograph. Nano-iron particles were observed under a FEI Quanta 200 FEG environmental scanning electron ...
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Intensely yellow β -bismuth trioxide in the form of about 41 nm large crystallites has been prepared by thermal decomposition of (BiO)2CO3 at 400 ◦C. From the band gap energy of 2.3 eV obtained under the assumption of an indirect band-to-band transition and the quasi-Fermi level of −0.28± 0.02 V (vs. NHE) a valence band edge position of 2.02 V is calculated. This semiconducting oxide assists a ...
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Gas-phase electrochemistry: The direct hydroxylation of benzene to phenol was investigated using an electrochemical cell. The production of phenol over a VO(x) anode was found to be significant at 50 °C. The resultant current efficiency for phenol production and selectivity toward phenol reached 76.5 and 94.7 %, respectively.
متن کاملCompetitive adsorption of phenol and 3-chlorophenol on purified MWCNTs.
A commercial multiwall carbon nanotube and its carboxylated derivate (CNTC and COOHC, respectively) was used after purification to study the competitive adsorption of phenol (P) and m-chlorophenol (CP) from 0.1 M aqueous NaCl solutions without external pH control. The adsorption takes place practically exclusively on the external surface of the nanotubes. The uptake of P is suppressed in compar...
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ژورنال
عنوان ژورنال: Environmental Science & Technology
سال: 1997
ISSN: 0013-936X,1520-5851
DOI: 10.1021/es972005a